After installing Skype and the Jabber client Psi, I set both programs to start within Session and Startup, Application Autostart. The first time I boot the computer, the programs launch as expected. However, if I log out and then log in again, the programs do not start. Why is this and how can I fix it?

  • Try Clear saved sessions and disable Automatically save session on logout, close all applications and logout/login. Xfce4 trips over its own saved sessions from time to time in my experience. – kba Feb 18 '16 at 22:37

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