From the man page:
When bash is invoked as an interactive login shell, or as a non-interactive shell with the --login option, it first reads and executes commands from the file /etc/profile, if that file exists. After reading that file, it looks for ~/.bash_profile, ~/.bash_login, and ~/.profile, in that order, and reads and executes commands from the first one that exists and is readable. The --noprofile option may be used when the shell is started to inhibit this behavior.
When a login shell exits, bash reads and executes commands from the file ~/.bash_logout, if it exists.
When an interactive shell that is not a login shell is started, bash reads and executes commands from /etc/bash.bashrc and ~/.bashrc, if these files exist. This may be inhibited by using the --norc option. The --rcfile file option will force bash to read and execute commands from file instead of /etc/bash.bashrc and ~/.bashrc.
For change the WM of your users: uninstall kdm/gdm/xdm/slim, setup the WM in ~/.xinitrc and run "startx" from your bash config.