"Not working" might be slightly inaccurate, since it still seems to mount and umount things properly, but it's inaccessible to users other than the root user, which defeats the purpose entirely.
It's still installed on the system, and works fine from the root account, but my regular user accounts don't have sufficient privileges to use it. I'm not aware of having changed any permissions relating to mounting, and remove --purge pmounting followed by a re-install does nothing (both with apt-get and with aptitude.
Any idea what I kicked over by accident?
