This should work -
awk -F"," -v OFS="," '
$NF=="()" {print $1,$2,"NONE";next}
{gsub(/\(|\)/,"",$NF);print}' INPUT_FILE
Explanation:
We set the Field Separator to , and Output Field Separator to ,. Setting OFS gives us the liberty to avoid printing your desired field separators explicitly.
We check for a pattern $NF=="()" (where $NF is the last field), if it is true we print out the first and the second field and print NONE as the last field. Since your sample data only had three fields this approach should be ok. However, if you have more than 5 fields then using a simple for loop would be ideal. Just make sure the for loop works like i=1;i<NF;i++ this way you can manually put the final field. We also use next keyword to move to the next line since we don't want the second action to run on the first line.
The second action statement is true for all the lines that don't match the first. Here we are using a global substitution built-in function which substitutes the brackets to nothing.
Hope this helps!
Test:
[jaypal:~/Temp] cat file
192.168.0.24,Up,()
192.168.0.25,Up,(host.domain.com)
192.168.0.24,Up,()
192.168.0.24,Up,()
192.168.0.25,Up,(host.domain.com)
192.168.0.25,Up,(host.domain.com)
[jaypal:~/Temp] awk -F"," -v OFS="," '
$NF=="()" {print $1,$2,"NONE";next}
{gsub(/\(|\)/,"",$NF);print}' file
192.168.0.24,Up,NONE
192.168.0.25,Up,host.domain.com
192.168.0.24,Up,NONE
192.168.0.24,Up,NONE
192.168.0.25,Up,host.domain.com
192.168.0.25,Up,host.domain.com